Synthesis of novel rhodium-carbene complexes as efficient catalysts for addition of phenylboronic acid to aldehydes


Ozdemir I. , DEMIR S., CETINKAYA B.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, cilt.215, ss.45-48, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 215
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1016/j.molcata.2003.12.037
  • Dergi Adı: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
  • Sayfa Sayıları: ss.45-48

Özet

Rhodium(I)-carbene complexes with 1,3-dialkylimidazolidin-2-ylidine ligand were prepared and characterized by conventional spectroscopic methods and elemental analyses. The rhodium-carbene complexes RhCl(COD)(1,3-dialkyl-imidazolinylidene), 2a-d, are an active catalyst for addition of phenylboronic acid to aldehydes. (C) 2004 Elsevier B.V. All rights reserved.