Synthesis of novel rhodium-carbene complexes as efficient catalysts for addition of phenylboronic acid to aldehydes

Ozdemir I., DEMIR S., CETINKAYA B.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, cilt.215, sa.1-2, ss.45-48, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 215 Sayı: 1-2
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1016/j.molcata.2003.12.037
  • Dergi Adı: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.45-48
  • Anahtar Kelimeler: N-heterocyclic carbene, rhodium complexes, imidazolidinylidine, arylation, aldehydes, OLEFIN METATHESIS CATALYSTS, HYDROSILYLATION CATALYSTS, ALKENE METATHESIS, METAL-COMPLEXES, CYCLOISOMERIZATION, ENETETRAMINES, DERIVATIVES, LIGANDS, CROSS, CO
  • İnönü Üniversitesi Adresli: Evet

Özet

Rhodium(I)-carbene complexes with 1,3-dialkylimidazolidin-2-ylidine ligand were prepared and characterized by conventional spectroscopic methods and elemental analyses. The rhodium-carbene complexes RhCl(COD)(1,3-dialkyl-imidazolinylidene), 2a-d, are an active catalyst for addition of phenylboronic acid to aldehydes. (C) 2004 Elsevier B.V. All rights reserved.