SYNTHESIS AND CHARACTERIZATION OF NOVEL ALKYL-SUBSTITUTED ARYL DIPHENYLPHOSPHINATE ESTERS
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.186, no.7, pp.1531-1537, 2011 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 186 Issue: 7
- Publication Date: 2011
- Doi Number: 10.1080/10426507.2010.521472
- Journal Name: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.1531-1537
- Keywords: Diphenylphosphinic chloride, phenol, phosphinic acid esters, phosphinate, PARA-NITROPHENYL DIPHENYLPHOSPHINATE, NUCLEOPHILIC DISPLACEMENT-REACTIONS, METAL-ION CATALYSIS, PHOSPHINE OXIDE, CHEMICAL-SHIFTS, SULFUR CENTERS, MAIN-CHAIN, PHOSPHORUS, DERIVATIVES, HEXACHLOROCYCLOTRIPHOSPHAZATRIENE
- Inonu University Affiliated: Yes
Abstract
In this work, the reactions of diphenylphosphinic chloride, (C6H5)(2)P(O)Cl, 1, with the sodium salts of sterically hindered phenol derivatives (2a-2j) were investigated. Novel alkyl-substituted aryl diphenyl phosphinate esters (C6H5)(2)P(O)OAr (3-12) were obtained from these reactions. Satisfactory analytical and spectroscopic results were obtained for all the new compounds.