SYNTHESIS AND CHARACTERIZATION OF NOVEL ALKYL-SUBSTITUTED ARYL DIPHENYLPHOSPHINATE ESTERS

BEGEÇ S., Alatas S., KILIÇ A.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.186, sa.7, ss.1531-1537, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 186 Sayı: 7
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1080/10426507.2010.521472
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1531-1537
  • Anahtar Kelimeler: Diphenylphosphinic chloride, phenol, phosphinic acid esters, phosphinate, PARA-NITROPHENYL DIPHENYLPHOSPHINATE, NUCLEOPHILIC DISPLACEMENT-REACTIONS, METAL-ION CATALYSIS, PHOSPHINE OXIDE, CHEMICAL-SHIFTS, SULFUR CENTERS, MAIN-CHAIN, PHOSPHORUS, DERIVATIVES, HEXACHLOROCYCLOTRIPHOSPHAZATRIENE
  • İnönü Üniversitesi Adresli: Evet

Özet

In this work, the reactions of diphenylphosphinic chloride, (C6H5)(2)P(O)Cl, 1, with the sodium salts of sterically hindered phenol derivatives (2a-2j) were investigated. Novel alkyl-substituted aryl diphenyl phosphinate esters (C6H5)(2)P(O)OAr (3-12) were obtained from these reactions. Satisfactory analytical and spectroscopic results were obtained for all the new compounds.