Dichlorido[1-(2-methylbenzyl)-3-(eta(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate

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Atıf İçin Kopyala

Arslan H., VanDerveer D., YAŞAR S., ÖZDEMİR İ., Cetinkaya B.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.65, 2009 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 65
• Basım Tarihi: 2009
• Doi Numarası: 10.1107/s160053680900350x
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• İnönü Üniversitesi Adresli: Evet

Özet

The title complex, [RuCl2(C25H26N2)]center dot CH2Cl2, is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru-Cl bonds and one Ru-carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C6H2(CH3)(3) arene group by a CH2 bridge. This leads to a system with very little apparent strain. A dichloromethane solvent molecule completes the crystal structure. Further stabilization is accomplished via C-center dot center dot center dot N and C-H center dot center dot center dot Cl interactions.