Theoretical approach to the magnetic properties of Mn(II), Cr(III), and Cu(II) complexes in the newly reported 12-and 15-membered macrocyclic ligands
PRAMANA-JOURNAL OF PHYSICS, vol.69, no.2, pp.301-306, 2007 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 69 Issue: 2
- Publication Date: 2007
- Doi Number: 10.1007/s12043-007-0130-5
- Journal Name: PRAMANA-JOURNAL OF PHYSICS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.301-306
- Inonu University Affiliated: Yes
Abstract
The magnetic properties of Cu2+, Cr3+, and Mn2+ ions in the newly reported 12- and 15-membered macrocyclic complexes are analysed by a theoretical approach. The calculated magnetic moment and magnetic anisotropy for vaxious situations, especially for Cu(II) ion, suggest that the magnetic properties may lead to a better interpretation about the geometry. It is also suggested that the zero-field splitting Hamiltonian may be used for magnetic properties of some metal ions, which have orbital singlet ground term in these complexes.