Theoretical approach to the magnetic properties of Mn(II), Cr(III), and Cu(II) complexes in the newly reported 12-and 15-membered macrocyclic ligands


Bayri A. , Karakaplan M.

PRAMANA-JOURNAL OF PHYSICS, cilt.69, ss.301-306, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 69 Konu: 2
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1007/s12043-007-0130-5
  • Dergi Adı: PRAMANA-JOURNAL OF PHYSICS
  • Sayfa Sayıları: ss.301-306

Özet

The magnetic properties of Cu2+, Cr3+, and Mn2+ ions in the newly reported 12- and 15-membered macrocyclic complexes are analysed by a theoretical approach. The calculated magnetic moment and magnetic anisotropy for vaxious situations, especially for Cu(II) ion, suggest that the magnetic properties may lead to a better interpretation about the geometry. It is also suggested that the zero-field splitting Hamiltonian may be used for magnetic properties of some metal ions, which have orbital singlet ground term in these complexes.