Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes
DALTON TRANSACTIONS, no.35, pp.7087-7093, 2009 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: Issue: 35
- Publication Date: 2009
- Doi Number: 10.1039/b906497b
- Journal Name: DALTON TRANSACTIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.7087-7093
- Inonu University Affiliated: Yes
Abstract
The reaction of Pd(OAc)(2) with 1-(benzhydryl)-3-(alkyl) benzimidazolium salts 1a-d yields trans-bis[1-(benzhydryl)-3-(alkyl)benzimidazolin-2-ylidene]dibromopalladium(II) complexes (2a-d) which were characterized by elemental analysis, NMR spectroscopy and the molecular structures of 2b, and 2d were determined by X-ray crystallography. The catalytic activity of PdBr(2)bis(benzimidazolin-2- ylidene) complexes 2a-d was evaluated in the direct arylation reaction of benzothiazole with bromobenzene derivatives.