Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes

DOGAN O., GÜRBÜZ N., ÖZDEMİR İ., Cetinkaya B., Sahin O., Buyukgungor O.

DALTON TRANSACTIONS, sa.35, ss.7087-7093, 2009 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 35
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1039/b906497b
  • Dergi Adı: DALTON TRANSACTIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7087-7093
  • İnönü Üniversitesi Adresli: Evet

Özet

The reaction of Pd(OAc)(2) with 1-(benzhydryl)-3-(alkyl) benzimidazolium salts 1a-d yields trans-bis[1-(benzhydryl)-3-(alkyl)benzimidazolin-2-ylidene]dibromopalladium(II) complexes (2a-d) which were characterized by elemental analysis, NMR spectroscopy and the molecular structures of 2b, and 2d were determined by X-ray crystallography. The catalytic activity of PdBr(2)bis(benzimidazolin-2- ylidene) complexes 2a-d was evaluated in the direct arylation reaction of benzothiazole with bromobenzene derivatives.