Synthesis, structure and spectroscopic characterization of 1,2-bis-(2,4,6-trimethylbenzylideneamino) ethanedichloropalladium(II)

ARICI, C; ULKU, D; Ozdemir, İSMAİL; DEMIR, SERKAN; CETINKAYA, SERPİL

doi:10.1080/00958970500404609

Synthesis, structure and spectroscopic characterization of 1,2-bis-(2,4,6-trimethylbenzylideneamino) ethanedichloropalladium(II)

ARICI C., ULKU D., Ozdemir I., DEMIR S., CETINKAYA B.

JOURNAL OF COORDINATION CHEMISTRY, vol.59, no.7, pp.797-802, 2006 (SCI-Expanded, Scopus)

Publication Type: Article / Article
Volume: 59 Issue: 7
Publication Date: 2006
Doi Number: 10.1080/00958970500404609
Journal Name: JOURNAL OF COORDINATION CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.797-802
Keywords: palladium(II), 2,4,6-trimethylbenzylideneamine, chloride, X-ray structure, spectroscopy, CATALYSTS, ETHYLENE, COPOLYMERIZATION, POLYMERIZATION
Inonu University Affiliated: Yes

Abstract

The structure of 1,2-bis(2,4,6-trimethylbenzylideneamino)ethanedichloropalladium(II) was determined by X-ray diffraction methods. The structure derived from NMR and IR spectra and elemental analysis is consistent with it. The complex is orthorhombic, space group Pcab, with a = 14.8662(12), b = 15.0861(13), c = 20.6255(14) angstrom, V = 4625.7(6) angstrom(3) and Z = 8. In the lattice, there exists a weak C-H center dot center dot center dot Cl hydrogen bond.