Synthesis, structure and spectroscopic characterization of 1,2-bis-(2,4,6-trimethylbenzylideneamino) ethanedichloropalladium(II)

ARICI, C; ULKU, D; Ozdemir, İSMAİL; DEMIR, SERKAN; CETINKAYA, SERPİL

doi:10.1080/00958970500404609

Synthesis, structure and spectroscopic characterization of 1,2-bis-(2,4,6-trimethylbenzylideneamino) ethanedichloropalladium(II)

ARICI C., ULKU D., Ozdemir I., DEMIR S., CETINKAYA B.

JOURNAL OF COORDINATION CHEMISTRY, cilt.59, sa.7, ss.797-802, 2006 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 59 Sayı: 7
Basım Tarihi: 2006
Doi Numarası: 10.1080/00958970500404609
Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.797-802
Anahtar Kelimeler: palladium(II), 2,4,6-trimethylbenzylideneamine, chloride, X-ray structure, spectroscopy, CATALYSTS, ETHYLENE, COPOLYMERIZATION, POLYMERIZATION
İnönü Üniversitesi Adresli: Evet

Özet

The structure of 1,2-bis(2,4,6-trimethylbenzylideneamino)ethanedichloropalladium(II) was determined by X-ray diffraction methods. The structure derived from NMR and IR spectra and elemental analysis is consistent with it. The complex is orthorhombic, space group Pcab, with a = 14.8662(12), b = 15.0861(13), c = 20.6255(14) angstrom, V = 4625.7(6) angstrom(3) and Z = 8. In the lattice, there exists a weak C-H center dot center dot center dot Cl hydrogen bond.