Synthesis of Phenanthroline-Functionalized Phosphazene Based Metallosupramolecular Polymers and Their Stimuli-Responsive Properties

SEÇKİN T., Sezer S., KÖYTEPE S.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.28, sa.6, ss.2825-2834, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 28 Sayı: 6
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1007/s10904-018-0938-0
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2825-2834
  • Anahtar Kelimeler: Supramolecular chemistry, Metal coordinated polymers, Metallo-supramolecular polymers, Cyclotriphosphazene, Phenanthroline ligands, METALLO-SUPRAMOLECULAR POLYMERS, COORDINATION POLYMERS, CHEMISTRY, LIGANDS, TRANSITION
  • İnönü Üniversitesi Adresli: Evet

Özet

A series of phenanthroline-functionalized phosphazene based metallo-supramolecular polymers (PFP-MSP) was synthesised using a two-step reaction strategy. In first step, three phenanthroline unit containing monomer (PFP-M) was prepared from 5,6-dihydroxy-1,10-phenanthroline and hexachlorocyclotriphosphazene by condensation reaction. Then, this PFP-M was reacted with different metal ion salts (Co, Ni, Cu, Fe, Eu, La, Tb, Lu ions) and resulting for the metallo-supramolecular polymers bearing phosphazene structure. Obtained PFP-MSPs were characterized by spectroscopic analysis, elemental analysis, Scanning electron microscopy measurement and SEM-energy dispersive X-ray spectrometry techniques. Stimuli responsible and opto-electronic properties of synthesized PFP-MSPs were also studied for different external stimulating factors, such as electrochemical or the addition of competitive complexing ligands by UV-Vis spectroscopy and electroanalytic techniques. As a result, prepared PFP-MSPs are good alternatives for photochromic, electrochromic, opto-electronic and smart material applications.