Fabrication of electrospun polycaprolactone/chitosan nanofiber-modified screen-printed electrode for highly sensitive detection of diazinon in food analysis

Topsoy O. K., Muhammad F., Kolak S., Ulu A., GÜNGÖR Ö., ŞİMŞEK M., ...Daha Fazla

MEASUREMENT, cilt.187, 2022 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 187
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1016/j.measurement.2021.110250
  • Dergi Adı: MEASUREMENT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Compendex, INSPEC
  • Anahtar Kelimeler: Diazinon, Electrochemical sensor, Screen-printed electrode, Electrospun, Nanofiber, MOLECULARLY IMPRINTED POLYMER, SOLID-PHASE EXTRACTION, ELECTROCHEMICAL SENSOR, PESTICIDE, FRUIT, WATER, PASTE
  • İnönü Üniversitesi Adresli: Evet

Özet

In the present study, a screen-printed electrode for Diazinon (DZN) detection was modified with nanofibers prepared via electrospinning technique. The chemical structure, morphology, and crystallinity of the nanofibers were characterized in detail. The electrochemical behaviors of the modified screen-printed electrode were evaluated by cyclic voltammetry, differential pulse voltammetry, and electrochemical impedance spectroscopy. The spinning time, pH value and scan rates were optimized at 6 min, 5.25, and 50 mVs(-1), respectively. The limit of detection as 2.888 nM was obtained over a linear concentration range (3 nM-100 nM). Besides, DZN selectivity, repeatability, and storage stabilities of the developed sensor were proven. Meanwhile, the sensor was successfully applied for the determination of DZN in the tomato juice sample with recovery values in the range of 93.27-108.30%. The developed sensor could be a promising candidate to detect the presence and level of DZN in real samples.