Acetalization and transacetalization reactions catalyzed by ruthenium, rhodium, and iridium complexes with (2-{{bis[3-(trifluoromethyl)phenyl]phosphino}methyl}-2-methylpropane-1,3-diyl}bis[bis[3-(trifluoromethyl)phenyl]phosphine] (MeC[CH2P(m-CF3C6H4)(2)](3))

Sulu, MUSTAFA; Venanzi, L.M.

Acetalization and transacetalization reactions catalyzed by ruthenium, rhodium, and iridium complexes with (2-{{bis[3-(trifluoromethyl)phenyl]phosphino}methyl}-2-methylpropane-1,3-diyl}bis[bis[3-(trifluoromethyl)phenyl]phosphine] (MeC[CH2P(m-CF3C6H4)(2)](3))

Atıf İçin Kopyala

Sulu M., Venanzi L.

HELVETICA CHIMICA ACTA, cilt.84, sa.4, ss.898-907, 2001 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 84 Sayı: 4
Basım Tarihi: 2001
Dergi Adı: HELVETICA CHIMICA ACTA
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.898-907
İnönü Üniversitesi Adresli: Evet

Özet

The complexes [RhCl(3 n)(MeCN)(n)(CF(3)triphos)](CF3SO3)(n) (n = 1, 2; CF(3)triphos = MeC[CH2P(m-CF3C6H4)(2)](3)) and [M(MeCN)(3) (CF(3)triphos)](CF3SO3)(n) (M = Ru, n = 2; M = Ir, n = 3) are catalyst precursors for some typical acetalization and transacetalization reactions. The activity of these complexes is higher than those of the corresponding species containing the parent ligand MeC[CH2P(C6H5)(2)](3)(Htriphos). Also the complexes [MCl3(tripod)] (tripod = Htriphos and CF(3)triphos) are active catalysts for the above reactions. The complex [RhCl2(MeCN)(CF(3)triphos)](CF3SO3) catalyzes the acetalization of benzophenone.