Ruthenium(II) N-heterocyclic carbene complexes in the transfer hydrogenation of ketones

Ozdemir I., YASAR S., CETINKAYA B.

TRANSITION METAL CHEMISTRY, cilt.30, sa.7, ss.831-835, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 30 Sayı: 7
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1007/s11243-005-6736-x
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.831-835
  • İnönü Üniversitesi Adresli: Evet

Özet

Six ruthenium-N-heterocyclic carbene complexes (2-7) have been prepared and the new compounds characterized by C, H, N analyses, H-1-n.m.r. and C-13-n.m.r. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes (2-7) in the presence of t-BuOK.