Metal-NHC heterocycle complexes in catalysis and biological applications: Systematic review

Jalal M., Hammouti B., Touzani R., Aouniti A., ÖZDEMİR İ.

MATERIALS TODAY-PROCEEDINGS, cilt.31, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.matpr.2020.06.398
  • Dergi Adı: MATERIALS TODAY-PROCEEDINGS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), INSPEC
  • Anahtar Kelimeler: NH-Carbenes, Metal, Synthesis, Applications, Catalysis, Biological, STRUCTURAL-CHARACTERIZATION, CARBENE COMPLEXES, LIGAND, HYDROGENATION, PALLADIUM(II), VINYLIDENES, REACTIVITY, ALKENES
  • İnönü Üniversitesi Adresli: Evet

Özet

N-heterocyclic carbenes are of central importance in many domains of chemistry such as organometallic, catalysis and bioinorganic. Their great importance is due to their ability to act as ligands with a large number of transition metals. These Metal-NHCs are used as catalysts in various organic transformations with good biological properties. A wide range of Metals - NHC has been found to be useful as a catalyst in various reactions using Ru, Pd, Ir, Au and Ag. This review examines the different classes of Metal - NHCs and their applications as effective catalysts in several types of organic processes, for example the formation of amide linkage, hydrogenation, isomerization, cycloisomerization, cyclopropanation, hydrosilylation, allylation and desallylation, enol-ester synthesis, heterocycle synthesis, C - C alkyne coupling. (C) 2020 The Authors. Published by Elsevier Ltd.