Investigation of Electrochemical and Thermal Properties of Ti50Ni40−xZr10Nbx SMAs

Abdullah S. S., Balci E., Qader I. N., Dagdelen F.

Journal of Materials Engineering and Performance, cilt.34, sa.5, ss.4449-4457, 2025 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34 Sayı: 5
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1007/s11665-024-09414-6
  • Dergi Adı: Journal of Materials Engineering and Performance
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, PASCAL, Aerospace Database, Applied Science & Technology Source, Aquatic Science & Fisheries Abstracts (ASFA), Chemical Abstracts Core, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.4449-4457
  • Anahtar Kelimeler: biocompatibility, NiTiZrNb, potentiodynamic test, shape memory alloy
  • İnönü Üniversitesi Adresli: Evet

Özet

Titanium and its alloys have already been widely used as implant materials due to their outstanding mechanical characteristics, thermal properties, and biocompatibility. In this study, Ti50Ni40−xZr10Nbx (x = 1, 3, 5 at.%) shape memory alloys (SMAs) with a constant atomic percentage of Ti and Zr were investigated. For investigation of the structural properties of produced SMAs, scanning electron microscope (SEM-EDX) analysis, optical microscope (OM) images, and x-ray diffraction (XRD) pattern were taken. B2, B19′, β-Nb, and Ti2N phases were detected in all alloys. In SEM-EDX and OM research, it was determined that β-Nb phase increased in dendritic structure as the Nb ratio increased. For the biocompatibility levels of alloys, the corrosion test method was carried out with the potentiodynamic test, which is one of the electrochemical methods. Tafel test and electrochemical impedance spectroscopy in a simulated body fluid (SBF) showed that the Nb additive increased the corrosion resistance of the alloy. Phase transformation temperatures (PTTs) of these alloys were investigated by using differential scanning calorimetry (DSC) measurements. In DSC research, it was determined that the alloys have a shape memory effect (SME), and the PPTs of the alloys decreased as the Nb ratio increased.