Development electrically conductive PAAm/Alg/CNC/rGO/PANI hydrogel composites and investigation their bioelectronic properties


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Oruç S., Boztepe C., Zengin R.

MATERIALS TODAY COMMUNICATIONS, cilt.36, ss.106540-106552, 2023 (SCI-Expanded)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 36
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.mtcomm.2023.106540
  • Dergi Adı: MATERIALS TODAY COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex, INSPEC
  • Sayfa Sayıları: ss.106540-106552
  • İnönü Üniversitesi Adresli: Evet

Özet

Characterizing the effects of parameters such as the swelling ratio, composition, and applied current frequency of

hydrogels is crucial for the development of flexible, stretchable, and electrically conductive hydrogels that are of

importance in a variety of biomedical applications. In this study, poly(Acrylamide) (PAAm), alginate (Alg) and

crystalline nanocellulose (CNC) based stretchable PAAm/Alg/CNC/rGO hydrogels containing different amounts

of reduced graphene oxide (rGO) in their structure were synthesized. To increase the electrical conductivity of

these hydrogels, their composites with polyaniline (PANI) were prepared. The chemical composition and

morphological characterizations were performed using FT-IR and SEM analysis techniques. Since the amount of

PANI formed in the structure of hydrogel composites was directly proportional to the amount of rGO in the

structure, swelling, mechanical and electrical conductivity properties changed depending on the amount of rGO.

The swelling ratio and mechanical strength of the PAAm/Alg/CNC/rGO/PANI hydrogel composite series varied

between 38 and 50 g water/ g polymer and 76.02–375.95 kPa, respectively. The electrical conductivities of their

25% swollen states at 10􀀀 4 MHz ranged from 15.4 to 20.20 S/m. Flex sensor, smart hydrogel fingers and

electrocardiogram (ECG) electrode applications were tested. The synthesized hydrogel composite systems were

quite successful in these biomedical applications as bioelectronic materials.