Functionalized ionic liquids based on imidazolium cation: Synthesis, characterization and catalytic activity for N-alkylation reaction

DEMIR S., DAMARHAN Y., ÖZDEMİR İ.

JOURNAL OF MOLECULAR LIQUIDS, cilt.204, ss.210-215, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 204
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.molliq.2015.01.051
  • Dergi Adı: JOURNAL OF MOLECULAR LIQUIDS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.210-215
  • Anahtar Kelimeler: Ionic liquid, Imidazole, Catalysis, N-alkylation, AROMATIC-AMINES, HECK REACTION, ANILINE, NANOPARTICLES, ALDEHYDES, SOLVENTS, METHANOL, ANION
  • İnönü Üniversitesi Adresli: Evet

Özet

The novel functionalized ionic liquids based on imidazolium cation are synthesized and characterized by studying its H-1, C-13, and P-31 NMR and elemental analysis. These ionic liquids have been reported as a highly efficient catalyst for N-alkylation reaction of aniline with butyl chloride. The reaction was efficiently performed in ionic liquid as an environmentally benign solvent with good yields without transition metal. (C) 2015 Elsevier B.V. All rights reserved.