Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for beta-alkylation of tertiary cyclic amines

ÖZDEMİR İ., Dusunceli S. D., KALOGLU N., ACHARD M., BRUNEAU C.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, ss.311-315, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası:
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.jorganchem.2015.10.011
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.311-315
  • Anahtar Kelimeler: N-Heterocyclic carbene, Ruthenium, Cyclic amine, Catalysis, OLEFIN METATHESIS, ALKENE METATHESIS, LIGAND PRECURSORS, FACILE SYNTHESIS, PALLADIUM, RACEMIZATION, EXCHANGE, IMIDAZOL(IN)IUM-2-CARBOXYLATES, HYDROGENATION, ACTIVATION
  • İnönü Üniversitesi Adresli: Evet

Özet

The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its H-1, C-13, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for beta C-H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by H-1 NMR, C-13 NMR spectroscopic methods. (C) 2015 Elsevier B.V. All rights reserved.