JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp.311-315, 2015 (SCI-Expanded)
Article / Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Science Citation Index Expanded (SCI-EXPANDED), Scopus
N-Heterocyclic carbene, Ruthenium, Cyclic amine, Catalysis, OLEFIN METATHESIS, ALKENE METATHESIS, LIGAND PRECURSORS, FACILE SYNTHESIS, PALLADIUM, RACEMIZATION, EXCHANGE, IMIDAZOL(IN)IUM-2-CARBOXYLATES, HYDROGENATION, ACTIVATION
Inonu University Affiliated:
The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its H-1, C-13, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for beta C-H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by H-1 NMR, C-13 NMR spectroscopic methods. (C) 2015 Elsevier B.V. All rights reserved.