Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for beta-alkylation of tertiary cyclic amines

ÖZDEMİR İ., Dusunceli S. D., KALOGLU N., ACHARD M., BRUNEAU C.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp.311-315, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume:
  • Publication Date: 2015
  • Doi Number: 10.1016/j.jorganchem.2015.10.011
  • Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.311-315
  • Keywords: N-Heterocyclic carbene, Ruthenium, Cyclic amine, Catalysis, OLEFIN METATHESIS, ALKENE METATHESIS, LIGAND PRECURSORS, FACILE SYNTHESIS, PALLADIUM, RACEMIZATION, EXCHANGE, IMIDAZOL(IN)IUM-2-CARBOXYLATES, HYDROGENATION, ACTIVATION
  • Inonu University Affiliated: Yes

Abstract

The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its H-1, C-13, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for beta C-H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by H-1 NMR, C-13 NMR spectroscopic methods. (C) 2015 Elsevier B.V. All rights reserved.