A New Palladium Complex Containing the Mixture of Carbene and Phosphine Ligands: Synthesis, Crystal Structure and Spectral FT-IR, NMR and UV-Vis Researches

AKTAŞ A.

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, cilt.38, sa.10, ss.1664-1672, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 38 Sayı: 10
  • Basım Tarihi: 2019
  • Doi Numarası: 10.14102/j.cnki.0254-5861.2011-2331
  • Dergi Adı: CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1664-1672
  • Anahtar Kelimeler: FTIR, N-heterocyclic carbene, NMR, UV-VIS, X-ray diffraction, N-HETEROCYCLIC CARBENES, METAL-COMPLEXES, ELECTRONIC-PROPERTIES, COPPER FREE, CATALYSTS
  • İnönü Üniversitesi Adresli: Evet

Özet

In this paper, a new Pd-based complex that contains N-heterocyclic carbene (NHC) and triphenylphosphine (PPh3) ligands was synthesized. The cis-(NHC)PdBr2(PPh3) complex has been prepared by the substitution of 3-chloropyridine ligand in (NHC)PdBr2(3-chloropyridine) complex with triphenylphosphine. This complex has been characterized by using H-1 NMR, P-31 {H-1} NMR, C-13 {H-1} NMR, FTIR, UV-Vis spectroscopy and elemental analysis techniques. The molecular and crystal structures of the cis-(NHC)PdBr2(PPh3) complex were determined by single-crystal X-ray diffraction method.