Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-(K) N-3} zinc(II)

KÜÇÜKBAY H., Yilmaz U., AKKURT M., Buyukgungor O.

TURKISH JOURNAL OF CHEMISTRY, cilt.39, sa.1, ss.108-120, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39 Sayı: 1
  • Basım Tarihi: 2015
  • Doi Numarası: 10.3906/kim-1405-47
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.108-120
  • Anahtar Kelimeler: Benzimidazole metal complexes, transition metal complexes, coordination compounds, crystal structure, CROSS-COUPLING REACTIONS, CRYSTAL-STRUCTURE, METAL-COMPLEXES, ANTIMICROBIAL ACTIVITIES, CATALYTIC-ACTIVITY, ANTITUMOR-ACTIVITY, COBALT(II), LIGAND, COORDINATION, DERIVATIVES
  • İnönü Üniversitesi Adresli: Evet

Özet

The Co(II), Fe(II), and Zn(II) complexes of 1-(3-phenyl)propylbenzimidazole (PPBI), 5-nitro-1-(3-phenyl) propylbenzimidazole (PPNBI), 1-[2-(4-morpholinyl)ethyl]benzimidazole (MEBI), 1-[2-(1-piperidinyl)ethyl]benzimidazole (PEBI), and 5-nitro-1-[2-(1-piperidinyl)ethyl]benzimidazole (PENBI) were synthesized and characterized by H-1 NMR, C-13 NMR, and elemental analyses. The magnitudes of the magnetic moments for paramagnetic complexes were between 4.07 and 5.11 B.M. Moreover, the crystal structure of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1 H-benzimidazole-(K) N-3} zinc(II) was determined by single crystal X-ray diffraction.