Phenolysis of 2, 2 '-Biphenoxy Thiophosphinic Chloride: Crystal Structures and DFT Calculations of 2, 2 '-Biphenyl 4-Tert-Butylphenyl Thiophosphinate and 2, 2 '-Biphenyl 3,4-di-Methylphenyl Thiophosphinate

Begeç S., Yüksel F., Chumakov Y., Alatas S., Kılıç A.

POLYCYCLIC AROMATIC COMPOUNDS, 2022 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1080/10406638.2022.2136721
  • Dergi Adı: POLYCYCLIC AROMATIC COMPOUNDS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, CAB Abstracts, Chemical Abstracts Core, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Sterically hindered phenols, thiophosphoryl chloride, phosphorothionates, 2,2 '-dihydroxybiphenyl, X-ray crystal structure, DFT calculations, NMR CHEMICAL-SHIFTS
  • İnönü Üniversitesi Adresli: Evet

Özet

In this work, firstly, thiophosphoryl chloride, PSCl3 (1), with 2,2'-dihydroxybiphenyl, 2,2 '-HOC6H4C6H4OH (2) were reacted. 2, 2 '-biphenoxy thiophosphinic chloride (3) was obtained from this reaction. Second, the reactions of compound (3) with sterically hindered phenol derivatives (4a-4h) were investigated. Novel alkyl-substituted phenyl 2, 2 '-biphenyl-thiophosphinate esters (C6H4O)(2)P(S)OAr (5-12) were obtained from these reactions. Structures of (5-12) were defined by IR, H-1, C-13, P-31 NMR spectroscopy, and elemental analysis. The molecular structures of 2, 2 '-biphenyl 4-tert-butylphenyl thiophosphinate (11) and 2, 2 '-biphenyl 3,4-di-methylphenyl thiophosphinate (6) were determined by single-crystal X-ray diffraction. Density functional theory (DFT) calculations of compounds 6 and 11 were made. The theoretical analysis of IR and NMR spectra was performed by DFT based on B3LYP level of theory.