Transfer hydrogenation of ketones catalyzed by 1-alkylbenzimidazole ruthenium(II) complexes

Ozdemir I., SAHIN N., CETINKAYA B.

MONATSHEFTE FUR CHEMIE, cilt.138, sa.3, ss.205-209, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 138 Sayı: 3
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1007/s00706-007-0590-9
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.205-209
  • İnönü Üniversitesi Adresli: Evet

Özet

Six [RuCl2(1-alkylbenzimidazole)(p-cymene)] complexes have been prepared and the new compounds characterized by C, H, N analyses, H-1 NMR, and C-13 NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of the complexes in the presence of t-BuOK.