Synthesis, characterization, and application to transfer hydrogenation of eta(6)-(3,4,5-trimethoxybenzyl)-eta(1)-N-heterocyclic carbene-ruthenium complex

DEMIR S., ÖZDEMİR İ., Cetinkaya B., ŞAHİN E., ARICI C.

JOURNAL OF COORDINATION CHEMISTRY, cilt.64, sa.14, ss.2565-2572, 2011 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64 Sayı: 14
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1080/00958972.2011.589510
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2565-2572
  • Anahtar Kelimeler: Transfer hydrogenation reaction, N-Heterocyclic carbene, Ruthenium, Chelating carbene, CATALYST, KETONES, SYSTEM, LIGAND
  • İnönü Üniversitesi Adresli: Evet

Özet

A new chelating ruthenium complex was synthesized using an electron-rich olefin and [RuCl2(p-cymene)](2) and characterized structurally and spectroscopically. The structure of the complex was verified using X-ray crystallography. The complex displayed high activities in transfer hydrogenation.