Structural evolution and microwave absorption properties of MnFe₂O₄/BaTiO₃ nanoparticle systems and their composites
Journal of Materials Science: Materials in Electronics, cilt.37, sa.7, 2026 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 37 Sayı: 7
- Basım Tarihi: 2026
- Doi Numarası: 10.1007/s10854-026-16924-7
- Dergi Adı: Journal of Materials Science: Materials in Electronics
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Compendex, INSPEC, MEDLINE
- İnönü Üniversitesi Adresli: Evet
Özet
In this study, MnFe₂O₄/BaTiO₃ nanoparticle systems were systematically investigated as microwave absorbers in the X-band (8–12.4 GHz). Nanoparticles were physically mixed at different weight ratios and examined both before and after annealing at 1100 C for 3 h. The microstructural and magnetic properties were evaluated using SEM, TEM, XRD, XPS, FTIR and M–H hysteresis measurements, respectively. Structural analyses revealed that the as-mixed samples consist of coexisting MnFe2O4 and BaTiO3 phases, while annealing induces an in-situ transformation into an Mn/Ti-substituted M-type barium hexaferrite phase. This phase evolution leads to a significant increase in saturation magnetization and coercivity, indicating a transition toward harder magnetic behavior. Microwave absorption performance was evaluated using reflection loss measurements. The non-annealed 50 MnFe2O4–50 BaTiO3 composite exhibits the best absorption performance, with a minimum reflection loss (RL) of approximately − 23 dB at 10.8–11.0 GHz. In contrast, annealed samples show reduced absorption efficiency, with minimum reflection loss values in the range of − 10 to − 16 dB. These results demonstrate that enhanced magnetic hardness does not necessarily improve microwave absorption in MnFe2O4/BaTiO3-based absorbers.