[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule


Ustun E., DUSUNCELI S. D. , ÖZDEMİR İ.

BULGARIAN CHEMICAL COMMUNICATIONS, cilt.49, ss.50-56, 2017 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 49
  • Basım Tarihi: 2017
  • Dergi Adı: BULGARIAN CHEMICAL COMMUNICATIONS
  • Sayfa Sayıları: ss.50-56

Özet

Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.