Cross coupling reactions catalyzed by (NHC)Pd(II) complexes

GÜRBÜZ N., KARACA E. Ö., ÖZDEMİR İ., Cetinkaya B.

TURKISH JOURNAL OF CHEMISTRY, cilt.39, sa.6, ss.1115-1157, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Derleme
  • Cilt numarası: 39 Sayı: 6
  • Basım Tarihi: 2015
  • Doi Numarası: 10.3906/kim-1510-31
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.1115-1157
  • Anahtar Kelimeler: N-heterocyclic carbene, palladium, cross-coupling reaction, N-HETEROCYCLIC-CARBENE, ASYMMETRIC SUZUKI-MIYAURA, NHC-PALLADIUM COMPLEXES, X-RAY STRUCTURES, C-N, ROOM-TEMPERATURE, EFFICIENT CATALYSTS, HIGHLY EFFICIENT, METAL-COMPLEXES, ORGANIC HALIDES
  • İnönü Üniversitesi Adresli: Evet

Özet

This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC Pd(II) complexes (NHC: N-heterocyclic carbene) for cross-coupling reactions such as Heck Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald-Hartwig aminations, which are extremely powerful in the formation of C-C and C-heteroatom bonds. Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide for chemists interested in these reactions. The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.