Synthesis and catalytic properties of N-functionalised carbene complexes of rhodium(I)
JOURNAL OF COORDINATION CHEMISTRY, cilt.60, sa.21, ss.2377-2384, 2007 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 60 Sayı: 21
- Basım Tarihi: 2007
- Doi Numarası: 10.1080/00958970701637809
- Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2377-2384
- İnönü Üniversitesi Adresli: Evet
Özet
Reaction of [RhCl(COD)] 2, with 1,3-dialkylimidazolinylidene (1) or 1,3-dialkylbenzimidazolinylidene (2) resulted in the formation of rhodium(I) 1,3-dialkylimidazolin-2-ylidene (3a-c) and 1,3-dialkylbenzimidazolin-2-ylidene (4a, b) complexes. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amounts of RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylbenzimidazolin-2-ylidene) to give the corresponding silylethers in good yield (57-98%).