Preparation and characterization of trimethylsilyl-substituted benzimidazole metal complexes and structural characterization of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II)

Sireci N., KÜÇÜKBAY H., AKKURT M., Yalcin S. P., TAHIR M. N., OTT H.

JOURNAL OF COORDINATION CHEMISTRY, cilt.63, sa.18, ss.3218-3228, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 18
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1080/00958972.2010.509432
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3218-3228
  • Anahtar Kelimeler: Benzimidazole metal complexes, Silyl-substituted benzimidazoles, Crystal structure, ANTIMICROBIAL ACTIVITY, CARBENE COMPLEXES, CRYSTAL-STRUCTURE, SOLVATE
  • İnönü Üniversitesi Adresli: Evet

Özet

The ligands 1-trimethylsilylmethylbenzimidazole, 5-methyl-1-trimethylsilylmethylbenzimidazole, and 5-nitro-1-trimethylsilylmethylbenzimidazole and their Co(II) and Zn(II) complexes were synthesized and characterized by 1H-NMR, 13C-NMR, and elemental analyses. The crystal structure of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II) has been determined by single crystal X-ray diffraction.