Preparation and characterization of trimethylsilyl-substituted benzimidazole metal complexes and structural characterization of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II)
JOURNAL OF COORDINATION CHEMISTRY, cilt.63, sa.18, ss.3218-3228, 2010 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 63 Sayı: 18
- Basım Tarihi: 2010
- Doi Numarası: 10.1080/00958972.2010.509432
- Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.3218-3228
- Anahtar Kelimeler: Benzimidazole metal complexes, Silyl-substituted benzimidazoles, Crystal structure, ANTIMICROBIAL ACTIVITY, CARBENE COMPLEXES, CRYSTAL-STRUCTURE, SOLVATE
- İnönü Üniversitesi Adresli: Evet
Özet
The ligands 1-trimethylsilylmethylbenzimidazole, 5-methyl-1-trimethylsilylmethylbenzimidazole, and 5-nitro-1-trimethylsilylmethylbenzimidazole and their Co(II) and Zn(II) complexes were synthesized and characterized by 1H-NMR, 13C-NMR, and elemental analyses. The crystal structure of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II) has been determined by single crystal X-ray diffraction.