Novel azolinium/rhodium system catalyzed addition of arylboronic acids to aldehydes

Ozdemir I., YIGIT M., CETINKAYA E., CETINKAYA B.

HETEROCYCLES, cilt.68, sa.7, ss.1371-1379, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 68 Sayı: 7
  • Basım Tarihi: 2006
  • Doi Numarası: 10.3987/com-06-10731
  • Dergi Adı: HETEROCYCLES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1371-1379
  • İnönü Üniversitesi Adresli: Evet

Özet

There novel 1,3-dialkylperhydrobenzimidazolinium (2a-c) and two 1,3-dialkylimidazolinium salts (4a,b) as NHC precursors were synthesized from N,N'-dialkyl-1,2-cyclohexanediamine dihydrochloride and 1,2-dialkylpropanediamine dihydrochloride. The in situ prepared three component system [RhCl(COD)](2)/imidazolinium salts (2, 4) and KOBut catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields.