Application of N,N-bis(diphenylphosphino) aniline palladium(II) complexes as pre-catalysts in Heck coupling reactions

GUEMGUEM B., BIRICIK N., DURAP F., Oezdemir I., Guerbuez N., ANG W. H., ...Daha Fazla

APPLIED ORGANOMETALLIC CHEMISTRY, cilt.21, sa.8, ss.711-715, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Sayı: 8
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1002/aoc.1253
  • Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.711-715
  • Anahtar Kelimeler: aminophosphines, bis(diphenylphosphino)aniline, catalysis, Heck reaction, N,P ligands, palladium complexes, X-ray structure, COORDINATION CHEMISTRY, AMINOPHOSPHINE LIGANDS, AMINATION REACTIONS, METAL-COMPLEXES, ARYL BROMIDES, P,N LIGANDS, POLYMERIZATION, HYDROGENATION, REACTIVITY, CHLORIDES
  • İnönü Üniversitesi Adresli: Evet

Özet

Palladium(II) complexes with N,N-bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre-catalysts have been determined by single-crystal X-ray diffraction. Copyright (c) 2007 John Wiley & Sons, Ltd.