Application of N,N-bis(diphenylphosphino) aniline palladium(II) complexes as pre-catalysts in Heck coupling reactions

GUEMGUEM B., BIRICIK N., DURAP F., Oezdemir I., Guerbuez N., ANG W. H., ...More

APPLIED ORGANOMETALLIC CHEMISTRY, vol.21, no.8, pp.711-715, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 21 Issue: 8
  • Publication Date: 2007
  • Doi Number: 10.1002/aoc.1253
  • Journal Name: APPLIED ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.711-715
  • Keywords: aminophosphines, bis(diphenylphosphino)aniline, catalysis, Heck reaction, N,P ligands, palladium complexes, X-ray structure, COORDINATION CHEMISTRY, AMINOPHOSPHINE LIGANDS, AMINATION REACTIONS, METAL-COMPLEXES, ARYL BROMIDES, P,N LIGANDS, POLYMERIZATION, HYDROGENATION, REACTIVITY, CHLORIDES
  • Inonu University Affiliated: Yes

Abstract

Palladium(II) complexes with N,N-bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre-catalysts have been determined by single-crystal X-ray diffraction. Copyright (c) 2007 John Wiley & Sons, Ltd.