1,3-Bis(4-tert-butylbenzyl)-4,5-dihydroimidazolium chloride monohydrate

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Atıf İçin Kopyala

Arslan H., VanDerveer D., YAŞAR S., Oezdemir İ., Cetinkaya B.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.65, 2009 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 65
• Basım Tarihi: 2009
• Doi Numarası: 10.1107/s1600536809000452
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• İnönü Üniversitesi Adresli: Evet

Özet

In the title compound, C(25)H(35)N(2)(+)center dot Cl(-)center dot H(2)O,the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N-C-N carbon and the opposite C-C bond. The N-C-N fragment of the imidazolidine ring shows some degree of both double- and single-bond character due to partial electron delocalization. One of the tert-butyl groups is disordered over two conformations with occupancies of 0.714 (8) and 0.286 (8). In the crystal, O-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen bonds help to establish the packing.