JOURNAL OF ANALYTICAL CHEMISTRY, cilt.62, sa.8, ss.777-780, 2007 (SCI-Expanded)
A study of the electrochemical reduction of the mesotrione pesticide on a hanging mercury drop electrode (HMDE) was performed as a basis for the development of a sensitive analytical method for natural samples. The electrochemical characteristics of herbicide mesotrione dissolved in a phosphate buffer (pH 7.0) have been determined by means of electrochemical techniques such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) over a wide range of pH from 2.0 to 10.0. The experimental parameters, such as electrolyte type and its pH, pulse amplitude, and scan rate were optimized. The method was applied to the determination of the pesticide in a spiked soil samples. Using this method, a linear calibration curve for mesotrione was obtained up to the 0.1 mu M range in pH 7 phosphate buffer solution with a detection limit (S/N = 3) of 50 nM. The method can be applied successfully to the determination of mesotrione in soils.