The modification of aluminium tri-sec-butoxide with different alcohols and chelating ligands: Hydrolysis and condensation of the products


Sayilkan H., Arpac E., Sener E.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.27, sa.10, ss.1437-1452, 1997 (SCI-Expanded) identifier identifier

Özet

In this work, alcoholysis reactions of aluminium-sec-butoxide, Al(OBu-s)(3), with 2-ethoxyethanol (EtOCH2CH2OH) and 2-butoxyethanol (BuOCH2CH2OH), complexation reactions of Al(OBu-s)(3) and of alcohol-modified Al(OBu-s)(3) with methacrylic acid (MAC) and ethyl acetoacetate (EAAH), and the hydrolysis reactions of Al(OBu-s)(3) and modified Al(OBu-s)(3) are studied in some detail.