Dichloridobis[5-nitro-1-trimethylsilylmethyl-1H-benzimidazole-kappa N-3]cobalt(II) N,N-dimethylformamide solvate

AKKURT, MEHMET; Yalcin, Serife; SIRECI, Nihat; KÜÇÜKBAY, HASAN; TAHIR, M.

doi:10.1107/s1600536810003922

Dichloridobis[5-nitro-1-trimethylsilylmethyl-1H-benzimidazole-kappa N-3]cobalt(II) N,N-dimethylformamide solvate

AKKURT M., Yalcin S. P., SIRECI N., KÜÇÜKBAY H., TAHIR M. N.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.66, 2010 (SCI-Expanded, ESCI, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 66
Basım Tarihi: 2010
Doi Numarası: 10.1107/s1600536810003922
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
İnönü Üniversitesi Adresli: Evet

Özet

The title compound, [CoCl2(C11H15N3O2Si)(2)]center dot C3H7NO, was synthesized from 5-nitro-1-trimethylsilylmethyl-1H-benzimidazole and cobalt(II) chloride in dimethylformamide. The Co-II atom is coordinated in a distorted tetrahedral environment by two Cl atoms and two N atoms. In the crystal structure, there are a number of C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen-bonding interactions between symmetry-related molecules.