Magnetic Cu/Co nanoparticles supported on nitrogen‐doped porous carbon derived from Cu/Co@aZIF: Investigation of catalytic activity and structural properties

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Buğday N., Yaşar S., Altin S., Duygulu O., Önal Y.

APPLIED ORGANOMETALLIC CHEMISTRY, cilt.37, sa.e7017, ss.1-14, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 37 Sayı: e7017
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1002/aoc.7017
  • Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, BIOSIS, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Metadex, DIALNET, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1-14
  • Anahtar Kelimeler: AAC reaction, copper, MOF, nitrophenol, porous carbon
  • İnönü Üniversitesi Adresli: Evet

Özet

By  calcining  copper-doped  amorphous  zeolitic  imidazolate  framework(Cu/Co@aZIF),   a   novel   magnetic   nanoporous   carbon   composite(Cu/Co@NPC) material was produced, characterized by different spectro-scopic techniques, and used for the first time as an efficient catalyst for theazide-alkyne cycloaddition (AAC) reaction and the reduction reaction ofnitrophenol (RRN) under air in water. With this catalyst, the AAC and RRNreactions were conducted in aqueous solutions, and good to excellent yieldsof related products were synthesized in a short reaction time. The potentialof the magnetic Cu/Co@NPC nanocatalyst for targeting RRN and AACreactions was uncovered by studying specific substrates for RRN and AACreactions. The Cu/Co@NPC magnetic nanocatalyst is recyclable at least fivetimes, with just a drop of 6% and 22% in catalytic efficiency in RRN andAAC, respectively.