Magnetic Cu/Co nanoparticles supported on nitrogen‐doped porous carbon derived from Cu/Co@aZIF: Investigation of catalytic activity and structural properties
APPLIED ORGANOMETALLIC CHEMISTRY, vol.37, no.e7017, pp.1-14, 2023 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 37 Issue: e7017
- Publication Date: 2023
- Doi Number: 10.1002/aoc.7017
- Journal Name: APPLIED ORGANOMETALLIC CHEMISTRY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, BIOSIS, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Metadex, DIALNET, Civil Engineering Abstracts
- Page Numbers: pp.1-14
- Keywords: AAC reaction, copper, MOF, nitrophenol, porous carbon
- Open Archive Collection: AVESIS Open Access Collection
- Inonu University Affiliated: Yes
Abstract
By calcining copper-doped amorphous zeolitic imidazolate framework(Cu/Co@aZIF), a novel magnetic nanoporous carbon composite(Cu/Co@NPC) material was produced, characterized by different spectro-scopic techniques, and used for the first time as an efficient catalyst for theazide-alkyne cycloaddition (AAC) reaction and the reduction reaction ofnitrophenol (RRN) under air in water. With this catalyst, the AAC and RRNreactions were conducted in aqueous solutions, and good to excellent yieldsof related products were synthesized in a short reaction time. The potentialof the magnetic Cu/Co@NPC nanocatalyst for targeting RRN and AACreactions was uncovered by studying specific substrates for RRN and AACreactions. The Cu/Co@NPC magnetic nanocatalyst is recyclable at least fivetimes, with just a drop of 6% and 22% in catalytic efficiency in RRN andAAC, respectively.