Palladium-catalyzed Suzuki-Miyaura reaction of aryl chlorides in aqueous media using tetrahydrodiazepinium salts as carbene ligands

Ozdemir I., Gurbuz N., GOK Y., CETINKAYA E., CETINKAYA B.

SYNLETT, sa.15, ss.2394-2396, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 15
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1055/s-2005-872673
  • Dergi Adı: SYNLETT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2394-2396
  • İnönü Üniversitesi Adresli: Evet

Özet

A highly effective, easy to handle, and environmentally benign process for palladium-mediated Suzuki cross-coupling was developed. The in situ prepared three-component system of Pd(OAc)(2), 1,3-dialkyltetrahydrodiazepinium chlorides (2a-e), and K2CO3 catalyzes quantitatively the Suzuki-Miyaura cross-coupling of deactivated aryl chloride.