Imidazolidinium ferrate complexes: Synthesis and catalytic properties

DEMIR S., GOKCE Y., ROISNEL T., SORTAIS J., DARCEL C., ÖZDEMİR İ.

COMPTES RENDUS CHIMIE, cilt.17, sa.6, ss.541-548, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 17 Sayı: 6
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.crci.2014.03.015
  • Dergi Adı: COMPTES RENDUS CHIMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.541-548
  • Anahtar Kelimeler: Ferrate complex, Imidazolidinium salt, Kochi cross-coupling reaction, N-HETEROCYCLIC-CARBENE, CROSS-COUPLING REACTIONS, ARYL GRIGNARD-REAGENTS, TRANSITION-METAL-COMPLEXES, IRON CATALYSTS, EFFICIENT HYDROSILYLATION, ALKENYL HALIDES, DICARBENE COMPLEXES, ALKYL-HALIDES, HYDROGENATION
  • İnönü Üniversitesi Adresli: Evet

Özet

The new well-defined and air stable anionic iron complexes bearing an imidazolidinium ligand (2a-d) have been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction studies. Starting from FeBr2, [imidazolidinium][FeBr4] complexes 2a and 2b were prepared. The reaction of imidazolidinium chlorides with Fe(OAc)(2), followed by a recrystallization in the air led to bis(imidazolidinium) mu-oxido-bis[trichloroferrate(III)] complexes 2c and 2d. The catalytic activity of these novel complexes has been evaluated in the cross-coupling reactions of alkyl halides with Grignard reagents. (C) 2014 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.