Sonogashira cross-coupling reaction catalyzed by N-heterocyclic carbene-Pd(II)-PPh3 complexes under copper free and aerobic conditions

Dehimat Z. I., YAŞAR S., Tebbani D., ÖZDEMİR İ.

INORGANICA CHIMICA ACTA, cilt.469, ss.325-334, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 469
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1016/j.ica.2017.09.048
  • Dergi Adı: INORGANICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.325-334
  • Anahtar Kelimeler: N-heterocyclic carbene, Palladium, Sonogashira cross-coupling reaction, C-C bond formation, CARBENE COMPLEXES, SUZUKI-MIYAURA, PALLADIUM(II) COMPLEXES, METAL-COMPLEXES, AMINE-FREE, ARYL, NHC, EFFICIENT, PHOSPHINE, LIGANDS
  • İnönü Üniversitesi Adresli: Evet

Özet

NHC-Pd-PPh3 complexes with the bulky benzyladamantyl substited N-heterocyclic carbene (NHC) were synthesized and characterised by NMR, HRMS and micro analyse. These complexes were proceeded to Sonogashira-Hagihara coupling reaction between aryl bromides and phenylacatylene in DMF. All palladium compounds are stable and have high catalytic activity on Sonogashira-Hagihara reaction by low catalyst loading. (C) 2017 Elsevier B.V. All rights reserved.