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GÜRBÜZ N., Yasar S., Ozcan E. Ö., ÖZDEMİR İ., Cetinkaya B.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no.19, pp.3051-3056, 2010 (SCI-Expanded)
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Publication Type:
Article / Article
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Volume:
Issue:
19
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Publication Date:
2010
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Doi Number:
10.1002/ejic.201000181
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Journal Name:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
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Journal Indexes:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Page Numbers:
pp.3051-3056
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Keywords:
Nitrogen heterocycles, Carbene ligands, Ruthenium, Hydrogenation, Ketones, ASYMMETRIC TRANSFER HYDROGENATION, HETEROCYCLIC CARBENE LIGANDS, CATALYTIC TRANSFER HYDROGENATION, IRIDIUM COMPLEXES, TRANSFER REDUCTION, ALPHA,BETA-UNSATURATED KETONES, STEREOSELECTIVE HYDROGENATION, ALKENE METATHESIS, CHIRAL LIGANDS, RU
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Inonu University Affiliated:
Yes
Abstract
A series of benzimidazolium ligand precursors were metalated with [RuCl2(p-cymene)](2) to give ruthenium(II) N-heterocyclic carbene complexes. All compounds were fully characterized by elemental analyses, H-1 NMR, C-13 NMR, and IR spectroscopy. The new benzimidazol-2-ylidene complexes have been found to be effective catalysis for the transfer hydrogenation of ketones by using 2-propanol as the hydrogen source in the presence of KOH.