Syntheses and catalytic properties of alternating copolymers of poly[4-maleimidopyridyl(p-cymene)dichloro Ru(II)] with gamma-methacryloxypropyl trimethoxysilane

Ozdemir, İSMAİL; CETINKAYA, B; SECKIN, TURGAY; KOYTEPE, SÜLEYMAN

doi:10.1016/s1381-1169(01)00392-2

Syntheses and catalytic properties of alternating copolymers of poly[4-maleimidopyridyl(p-cymene)dichloro Ru(II)] with gamma-methacryloxypropyl trimethoxysilane

Atıf İçin Kopyala

Ozdemir I., CETINKAYA B., SECKIN T., KOYTEPE S.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, cilt.179, ss.263-270, 2002 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 179
Basım Tarihi: 2002
Doi Numarası: 10.1016/s1381-1169(01)00392-2
Dergi Adı: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.263-270
İnönü Üniversitesi Adresli: Evet

Özet

A new monomer, 4-maleimidopyridyl(p-cymene)dichloro Ru(II), was synthesized by the reaction of maleic anhyride with p-dimethylaminopyridine(p-cymene)dichloro ruthenium(II). The homopolymer ofmaleimidopyridyl(p-cymene)dichloro Ru(II) and its copolymers with gamma-methacryloxypropyl trimethoxysilane were prepared by radical polymerization with benzoyl peroxide as an initiator at 75 degreesC. The structures of the synthesized monomer and polymers were identified by Fourier transform infrared, H-1 NMR, and C-13 NMR spectroscopies. Thermal behavior of the polymers were determined by differential thermal analysis, and thermogravimetric analysis, glass transition temperature was determined by differential scanning calorimeter.