Synthesis and spectral characterization of new benzimidazolium compounds containing sulfur
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.195, sa.7, ss.580-585, 2020 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 195 Sayı: 7
- Basım Tarihi: 2020
- Doi Numarası: 10.1080/10426507.2020.1728760
- Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
- Sayfa Sayıları: ss.580-585
- Anahtar Kelimeler: Dithioester, carbodithioate, benzimidazole, N-heterocyclic carbene, zwitterions, TRANSFER RAFT POLYMERIZATION, FREE-RADICAL POLYMERIZATION, DIELS-ALDER REACTIONS, DITHIOCARBAMATES SYNTHESIS, ANTIMICROBIAL ACTIVITIES, ANTIBACTERIAL ACTIVITY, COMPLEXES, CARBODITHIOATE, DITHIOESTERS, DERIVATIVES
- İnönü Üniversitesi Adresli: Evet
Özet
N-heterocyclic carbene (compound b) was synthesized from reaction of 1-(3-phenylpropyl)-3-methylbenzimidazolium iodide (a) and a strong base in an argon atmosphere. Then, 1-(3-phenylpropyl)-3-methylbenzimidazolium-2-carbodithioate (c) was prepared with carbene and CS2. Finally, a group of alkyl 1-(3-phenylpropyl)-3-methylbenzimidazolium-2-carbodithioate halides was synthesized with alkyl halides and compound c, occurring products 1-6. Structural characterization of compounds was performed H-1, and C-13 NMR, IR, and MS spectroscopy and elemental analysis.