Synthesis of cis- and trans-dichloro(dimethylphenylphosphine) x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral and structural characterization

CETINKAYA, B; Ozdemir, İSMAİL; TAHIR, MN; ULKU, D

doi:10.1016/s0022-328x(98)00471-9

Synthesis of cis- and trans-dichloro(dimethylphenylphosphine) x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral and structural characterization

CETINKAYA B., Ozdemir I., TAHIR M., ULKU D.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.561, ss.7-11, 1998 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 561
Basım Tarihi: 1998
Doi Numarası: 10.1016/s0022-328x(98)00471-9
Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.7-11
İnönü Üniversitesi Adresli: Evet

Özet

Interaction of [{Pt(mu-Cl)Cl(PMe2Ph)}(2)] with 1-methyl-1,4,5,6-tetrahydropyrimidine, L (R = Me), in boiling toluene produced a mixture of cis- and trans- isomers of [PtCl2(PMe2Ph){N = CH(Me)CH2CH2CH2}] trans-complex 2 isomerizes to give thermody-namically more stable corresponding cis-complex 1 in boiling ethanol. Spectroscopic and X-ray diffraction data permit generalizations about cis- and trans- isomeric pairs to be made. In addition, the trans influence of the ligand L is reliably assessed. (C) 1998 Elsevier Science S.A. All rights reserved.