THE SYNTHESIS OF SOME BENZIMIDAZOLIUM SALTS AND USE AS CARBENE PRECURSORS IN THE HECK AND SUZUKI REACTIONS
HETEROCYCLES, cilt.81, sa.4, ss.943-953, 2010 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 81 Sayı: 4
- Basım Tarihi: 2010
- Doi Numarası: 10.3987/com-09-11896
- Dergi Adı: HETEROCYCLES
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.943-953
- İnönü Üniversitesi Adresli: Evet
Özet
Novel 1-(2-diisopropylaminoethyl)-3-alkylbenzimidazolium salts as N-heterocyclic carbene precursors 2a-g were prepared by quarternazition of 1-(2-diisopropylaminoethyl)benzimidazoles in DMF with alkyl halides. The salts were characterized spectroscopically and in situ formed complexes from Pd(OAc)(2) and 2 have been tested as catalyst in homogenous Heck and Suzuki reactions.