A kinetic study of copper cementation with zinc in aqueous solutions


Demirkiran N., EKMEKYAPAR A., Kunkul A., Baysar A.

INTERNATIONAL JOURNAL OF MINERAL PROCESSING, cilt.82, sa.2, ss.80-85, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 82 Sayı: 2
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.minpro.2006.10.005
  • Dergi Adı: INTERNATIONAL JOURNAL OF MINERAL PROCESSING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.80-85
  • Anahtar Kelimeler: copper, zinc, cementation, kinetics, DISSOLUTION KINETICS, THIOSULFATE SOLUTIONS, LEACHING KINETICS, ALUMINUM DISC, IRON, MALACHITE, PRECIPITATION, MORPHOLOGY, GOLD, ORE
  • İnönü Üniversitesi Adresli: Evet

Özet

Cementation of copper from zinc containing copper solutions using metallic zinc was studied in this work. The effect of copper, zinc and ammonium chloride concentration, stirring speed, pH and temperature on the cementation of copper was determined. Cementation rate increased with initial copper concentration, stirring speed and temperature. pH variation from 1 to 4 increased the cementation rate but at higher pH, the rate was not significantly effected. The cementation rate of copper increased with Zn2+ ion concentration. However, the rate of this rise was slightly less compared to the rise that occurred in the Zn2+ ions free copper solution.