Synthesis and catalytic properties of 1-alkylperimidineruthenium (II) complexes

Alici B., Ozdemir I., KARAASLAN K., CETINKAYA E., CETINKAYA B.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, cilt.231, ss.261-264, 2005 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 231
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.molcata.2004.12.036
  • Dergi Adı: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.261-264
  • Anahtar Kelimeler: perimidine, olefin isomerization, ruthenium complexes, cycloisomerization, ALKENE METATHESIS, TRANSFER HYDROGENATION, RUTHENIUM COMPLEXES, CARBENE COMPLEXES, RU(II) COMPLEX, CYCLOISOMERIZATION, ALLENYLIDENE, CYCLIZATION, 1,6-DIENES, MECHANISM
  • İnönü Üniversitesi Adresli: Evet

Özet

Four new [RuCl2(perimidine)(p-cymene)] complexes have been prepared and characterized. Upon reaction with 1,1-diphenylprop-2-yn-1-ol they generate catalyst precursors. which perform the cycloisomerization of diallyltosylamide into N-tosyl-alpha-methylenepyrrolidine. (c) 2005 Elsevier B.V. All rights reserved.