Fructose-Based Polyurethane Membranes: Synthesis, Characterization, and Their Use as Voltammetric pH Electrode

GÜNGÖR Ö., PASAHAN A., CENGIZ M. A., KÖYTEPE S., SEÇKİN T.

INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS, cilt.64, sa.11, ss.563-569, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64 Sayı: 11
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1080/00914037.2014.996705
  • Dergi Adı: INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.563-569
  • Anahtar Kelimeler: Fructose, pH sensor, polyurethane, selective polyurethane film, IN-VITRO DEGRADATION, POLYMERS, SENSOR, ELASTOMERS, IMPLANTS, LIGNIN, FILMS
  • İnönü Üniversitesi Adresli: Evet

Özet

In this study, polyurethane films prepared from the 4,4-diphenylmethane diisocyanate (MDI), ethylene glycol, and different ratio fructose were used to prepare a novel amperometric pH electrode. Fructose-based films were characterized by FT-IR, DSC, DTA, and TGA. Prepared polyurethanes exhibited suitable T-g(degrees C), good thermal stability and good adhesive properties. The incorporation of saccharides into the PU structure results in a higher crosslinking density and a higher content of hard segments. Furthermore, the behavior of films prepared from polyurethane solutions containing 1%, 3%, 5%, and 10% fructose toward pH changes were examined by normal pulse voltammograms technique and diferantial pulse voltammetry.