Theoretical magnetic behavior and correct spectroscopic assignment of transition of some cobalt(III) complexes


Bayri A.

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, cilt.80, ss.1445-1447, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 80 Konu: 9
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1134/s0036024406090159
  • Dergi Adı: RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
  • Sayfa Sayıları: ss.1445-1447

Özet

The magnetic moments of the Co3+ ion in some newly reported complexes is investigated using a theoretical approach for two extreme ligand field strengths. It is found that the experimentally reported spectroscopic results do not correspond to the magnetic behavior. From detailed theoretical analysis, it is suggested that the reported spectroscopic assignments and magnetic data have to be reconsidered and seriously reinterpreted. It is also suggested that the magnetic moment and spectroscopic transition should not be considered separately.