PALLADIUM/BENZIMIDAZOLIUM SALT CATALYST SYSTEMS AND N-HETEROCYCLIC CARBENE-PALLADIUM(II)-PYRIDINE (PEPPSI) COMPLEXES FOR ANTI-MARKOVNIKOV HYDROAMINATIONS OF STYRENE IN IONIC LIQUID


GÖK Y., YİĞİT B., Celikal O. O. , YİĞİT M.

HETEROCYCLES, vol.98, no.3, pp.403-415, 2019 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 98 Issue: 3
  • Publication Date: 2019
  • Doi Number: 10.3987/com-19-14042
  • Journal Name: HETEROCYCLES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.403-415
  • Inonu University Affiliated: Yes

Abstract

Both in situ prepared Pd-NHC and NHC-Pd-PEPPSI complexes were tested as catalysts in the intermolecular hydroamination reactions between styrene with various anilines in ionic liquid. All of the compounds tested here are catalytically active for the intermolecular hydroamination of styrene with aromatic amines. The anti-Markovnikov addition products were obtained selectively by using 1 mol% of the palladium complex.