The reactions of hexachlorocyclotriphosphazatriene with ligands including mercapto groups


Begec S., Alatas S.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.181, ss.2387-2394, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 181 Konu: 10
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/10426500600695146
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.2387-2394

Özet

In this work, the reactions of hexachlorocyclotriphosphazatriene (trimer), N(3)P(3)Cl(6) 1, with 2-mercapto-1-methylimidazole (methimazole) 2, 2-mercaptopyrimidine 3, and 2-mercaptopyridine 4 were discussed. Mono- (5) and pentasubstituted (6) phosphazenes were obtained from the reaction of 1 with 2-mercapto-1-methylimidazole. Both mono- (7) and disubstituted geminal (8) phosphazenes were obtained from the reaction of 1 with 2-mercaptopyrimidine. But phoshazene or any phosphorus compound could not be isolated from the reaction of 1 with 2-mercaptopyridine.