Dinuclear Rhodium(I)–N-Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts

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Español-Sánchez B., Karataş M. O., Di Giuseppe A., Togaev U., Passarelli V., Oro L. A., ...Daha Fazla

European Journal of Inorganic Chemistry, cilt.29, sa.7, 2026 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 29 Sayı: 7
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1002/ejic.202500598
  • Dergi Adı: European Journal of Inorganic Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, MEDLINE
  • Anahtar Kelimeler: halogen bond, hydroamidation, hydropyridonation, N-heterocyclic carbene, shim chemistry
  • İnönü Üniversitesi Adresli: Hayır

Özet

A series of new RhI–N-Heterocyclic carbene dinuclear complexes of type [Rh(µ-Cl)(η2-coe)(NHC)]2, containing IPrBIAN, IPrCl, and IPr* ligands, has been prepared. The crystal structure of the IPrCl functionalized rhodium–dinuclear complex reveals an intermolecular Cl···Cl halogen bond. The chlorido-bridges can be cleaved by pyridine to afford the corresponding mononuclear derivatives RhCl(η2-coe)(NHC)(py). These complexes are efficient alkyne hydropyridonation catalysts, with the IMes complex exhibiting the highest reactivity within the series.