Synthesis of bridged palladium-PEPPSI complexes and catalytic studies in C-C cross-coupling reactions

Imik F., YAŞAR S., ÖZDEMİR İ.

INORGANICA CHIMICA ACTA, cilt.495, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 495
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.ica.2019.118969
  • Dergi Adı: INORGANICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Anahtar Kelimeler: Palladium N-heterocyclic carbene complex, Suzuki coupling, Sonogashira coupling, Heck coupling, HETEROCYCLIC CARBENE COMPLEXES, SUZUKI-MIYAURA, ROOM-TEMPERATURE, METAL-COMPLEXES, NHC, ORGANOBORANES, NANOPARTICLES, PRECATALYST, LIGANDS, BASE
  • İnönü Üniversitesi Adresli: Evet

Özet

A series of dimetallic NHC-Pd-PEPPSI complexes with phenylene-bridged N-heterocyclic carbenes (NHC) were synthesized and fully characterized by H-1 NMR, C-13 NMR, HRMS, FTIR, and elemental analysis. The N tags were 2,3,4,5,6-pentamethylbenzyl, 3,5-dimethylbenzyl, 4-tert-butylbenzyl and 3-methoxybenzyl groups. The catalytic properties of the complexes were investigated in the Suzuki-Miyaura reactions of aryl bromides with arylboronic acid and in the Heck coupling reactions of aryl bromide with styrene and in the Sonogashira reactions of aryl bromides with phenylacetylene. Generally, dimetallic complexes exhibit good catalytic activities in the Suzuki-Miyaura, Heck, and Sonogashira coupling reactions.