Reactions of electron-rich olefins with proton-active compounds

Kucukbay H., CETINKAYA E., CETINKAYA B., LAPPERT M.

SYNTHETIC COMMUNICATIONS, vol.27, no.23, pp.4059-4066, 1997 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 27 Issue: 23
  • Publication Date: 1997
  • Doi Number: 10.1080/00397919708005451
  • Journal Name: SYNTHETIC COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.4059-4066
  • Inonu University Affiliated: Yes

Abstract

From the reaction of electron-rich olefins, bis(1,3-dimethylbenzimidazolidine-2-ylidene), I, or bis(3-methylbenzothiazolidine-2-ylidene), LI with proton active compounds, such as dimethyl phosphite, diethyl phosphite, acetonitrile and benzaldehyde were obtained 2-substituted benzimidazole or benzothiazole derivatives. The compounds synthesized were identified by H-1, C-13, P-31-NMR, mass, FT-LR spectroscopic techniques and micro analysis.