Palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura reactions using naphthalenomethyl-substituted imidazolidin-2-ylidene ligands in aqueous media


AKTAŞ A. , Akkoc S., GÖK Y.

JOURNAL OF COORDINATION CHEMISTRY, cilt.66, ss.2901-2909, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 66 Konu: 16
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1080/00958972.2013.819092
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Sayfa Sayıları: ss.2901-2909

Özet

Naphthalenomethyl-substituted imidazolidinium salts (1a-g) were prepared and characterized by conventional spectroscopic methods, H-1 NMR, C-13 NMR, FTIR, and elemental analysis techniques. The in situ prepared three component systems naphthalenomethyl-substituted imidazolidinium salts, Pd(OAc)(2), and K2CO3 catalyzed quantitatively the Mizoroki-Heck and Suzuki-Miyaura coupling of aryl halides under mild conditions in aqueous media.